Certainly there are some nicer high interest accounts around now the base rate of interest from the Bank of England has gone up. So it's certainly worth looking at those - I know the ING accounts used to be pretty attractive, but am also under the impression that they're not so competitive now.
Really, high interest savings are probably your best bet at this stage - once you start juggling with investment vehicles you have to start committing to the long term. By rainy-day I'm presuming you don't want such restrictions.
Hope that helps.
